6.1.1 - Microwave-based control of an SCR-based flue gas aftertreatment system for biomass combustion

Event
EUROSENSORS 2026
2026-09-06 - 2026-09-09
Zurich
Band
Lectures
Chapter
Chemical Sensors
Author(s)
B. Streibl, R. Moos, T. Wöhrl, G. Hagen - University of Bayreuth,Bayreuth (Germany), T. Ritter - H+H Engineering & Service GmbH,Sonnefeld (Germany)
Pages
186 - 187
DOI
10.5162/eurosensors2026/6.1.1
ISBN
978-3-910600-12-6
Price
free

Abstract

Tungsten trioxide (WO 3 ) polymorphs have been widely studied for molecular sensing, yet the origin of their different chemoresistive behaviors remains unclear. Here, structural and spectroscopic characterization, in situ DRIFTS, and density functional theory (DFT) simulations reveal that both γ- and ε-WO ₃ exhibit similar surface-level activation of acetone, whereas only ε-WO 3 stabilizes analyte-induced electronic states derived from W(5d) orbitals. These subsurface electronic rearrangements may explain its superior transduction efficiency despite similar receptor chemistry. Our findings provide a new framework for rational transducer design rooted in intrinsic electronic structure.

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